SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name BITUMEN MASTIC
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Supplier
ATDM CO.LTD
info@atdmco.com
1.4. Emergency telephone number(24 Hours)
SECTION 2: HAZARDS IDENTIFICATION OF BITUMEN MASTIC
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) Carc. Cat. 3;R40. N;R51/53. R10.
2.2. Label elements
Contains FUEL, DIESEL NO 2; GASOIL – UNSPECIFIED Labelling
Risk Phrases
Safety Phrases
2.3. Other hazards
Harmful Dangerous for the environment
R10 Flammable.
R40 Limited evidence of a carcinogenic effect.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S46 If swallowed, seek medical advice immediately and show this container or label.
S51 Use only in well-ventilated areas.
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
Product contains silica which in the form the product is supplied is not hazardous, however inhalation of dust generated from dried material must be avoided.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention. Ingestion
DO NOT induce vomiting. Get medical attention immediately. Skin contact
Promptly flush contaminated skin with soap or mild detergent and water. Promptly remove clothing if penetrated and flush the skin with water. Get medical attention promptly if symptoms occur after washing.
Eye contact
Rinse the eye with water immediately. Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
Protective equipment for fire-fighters
Wear self contained breathing apparatus
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Avoid skin and eye contact. Ensure adequate ventilation. Wear personal protective equipment. Wear self contained breathing apparatus.
6.2. Environmental precautions
Prevent entry into drains and water courses.
6.3. Methods and material for containment and cleaning up
Pick up with vacuum or absorbent solid, store in closed container for disposal.
6.4. Reference to other sections
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level.
7.2. Conditions for safe storage, including any incompatibilities
Store at moderate temperatures in dry, well ventilated area. Storage Class
Toxic storage.
7.3. Specific end use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Name
STD
TWA – 8 Hrs
STEL – 15 Min
Notes
PHOSPHORIC ACID …%
WEL
1 mg/m3
2 mg/m3
PROPAN-2-OL
WEL
400 ppm
999 mg/m3
500 ppm
1250 mg/m3
WEL = Workplace Exposure Limit.
Ingredient Comments
WEL = Workplace Exposure Limits
8.2. Exposure controls
Protective equipment
Engineering measures
Provide adequate general and local exhaust ventilation. Respiratory equipment
If ventilation is insufficient, suitable respiratory protection must be provided. Wear mask supplied with: Gas cartridge suitable for organic substances.
Hand protection
Protective gloves must be used if there is a risk of direct contact or splash. Use protective gloves made of: Nitrile. Use thin cotton gloves inside the rubber gloves if allergy risk.
Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact. Hygiene measures
Wash promptly if skin becomes contaminated. Wash hands at the end of each work shift and before eating, smoking and using the toilet.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Fibrous Paste
Colour Black. Odour Solvent.
Solubility Insoluble in water
Relative density 1.45
Flash point (°C) 50 CC (Closed cup).
9.2. Other information
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous decomposition products
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
General information
Known or suspected carcinogen for humans.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Dangerous for the environment: May cause long-term adverse effects in the aquatic environment.
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: DISPOSAL CONSIDERATIONS
General information
This material is classified as special waste as defined by Special Waste Regulations 1996 and must be disposed of by an authorised contractor
13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
14.1. UN number
UN No. (ADR/RID/ADN) 1133
UN No. (IMDG) 1133
UN No. (ICAO) 1133
14.2. UN proper shipping name
Proper Shipping Name ADHESIVES (NAPHTHA (PETROLEUM), HYDROSULFURIZED HEAVY; LOW BOILING)
14.3. Transport hazard class(es)
ADR/RID/ADN Class 3
ADR/RID/ADN Class Class 3: Flammable liquids. ADR Label No. 3
IMDG Class 3
ICAO Class/Division 3
Transport Labels
FLAMMABLE LIQUID 3
14.4. Packing group
ADR/RID/ADN Packing group III
IMDG Packing group III ICAO Packing group III
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
14.6. Special precautions for user
EMS F-E, S-D
Emergency Action Code •3YE Hazard No. (ADR) 30
Tunnel Restriction Code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to
Health.
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes
Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37.
